{"id":418,"date":"2019-11-22T15:08:59","date_gmt":"2019-11-22T06:08:59","guid":{"rendered":"https:\/\/home.hirosaki-u.ac.jp\/yaneura\/?p=418"},"modified":"2021-04-14T17:14:50","modified_gmt":"2021-04-14T08:14:50","slug":"xrd%e3%81%ab%e3%81%8a%e3%81%91%e3%82%8bx%e7%b7%9a%e3%81%ae%e4%be%b5%e5%85%a5%e6%b7%b1%e3%81%95","status":"publish","type":"post","link":"https:\/\/home.hirosaki-u.ac.jp\/yaneura\/418\/","title":{"rendered":"XRD\u306b\u304a\u3051\u308bX\u7dda\u306e\u4fb5\u5165\u6df1\u3055"},"content":{"rendered":"

X\u7dda\u56de\u6298\u6cd5\u3067\u306f\uff0c\u8a66\u6599\u8868\u9762\u304b\u3089\u3069\u306e\u7a0b\u5ea6\u306e\u6df1\u3055\u306e\u60c5\u5831\u304c\u5f97\u3089\u308c\u308b\u306e\u3067\u3057\u3087\u3046\u304b\uff1f<\/p>\n

<\/p>\n

\u305d\u308c\u306f\uff0cX\u7dda\u304c\u8a66\u6599\u304b\u3089\u53d7\u3051\u308b\u5438\u53ce\u306e\u7a0b\u5ea6\u306b\u3088\u308a\u307e\u3059\uff0e\u4ee5\u4e0b\uff0c\u30ea\u30ac\u30af\u30b8\u30e3\u30fc\u30ca\u30eb\u306e\u300c\u8584\u819cX\u7dda\u6e2c\u5b9a\u6cd5 \u57fa\u790e\u8b1b\u5ea7\u300d[1]\u304b\u3089\u5f15\u7528\u3057\u307e\u3059\u3068\uff0c\u56de\u6298X\u7dda\u306e\u3046\u3061\u306e99%\u306e\u5f37\u5ea6\u304c\u5f97\u3089\u308c\u308bX\u7dda\u4fb5\u5165\u6df1\u3055\u3092\u6709\u52b9\u539a t<\/i> \u3068\u3057\u3066\u5b9a\u7fa9\u3059\u308b\u3068\uff0c\u305d\u308c\u306fX\u7dda\u306e\u5165\u5c04\u89d2\u03b1<\/i>\u3068\u56de\u6298\u89d22\u03b8<\/i>\uff0c\u305d\u3057\u3066\u8a66\u6599\u306e\u7dda\u5438\u53ce\u4fc2\u6570\u03bc<\/i> \uff08\u9577\u3055\u306e\u9006\u6570\u306e\u6b21\u5143\u3092\u3082\u3064\uff09\u306b\u4f9d\u5b58\u3057\u3066\uff0c<\/p>\n

  <\/span>   <\/span>\"\[<\/p>\n

\u3068\u306a\u308a\u307e\u3059\uff0e\u3053\u306e4.61\u3068\u3044\u3046\u5024\u306e\u6b63\u4f53\u306f\uff0clog(1\/(1-0.99)) \u3067\u3059\uff0e\u307e\u305f\uff0c\u7279\u306b\u5bfe\u79f0\u53cd\u5c04\u306e\u5834\u5408\u306f\uff0c2\u03b8<\/i> = 2 \u03b1<\/i> \u3067\u3059\u306e\u3067\uff0c<\/p>\n

  <\/span>   <\/span>\"\[<\/p>\n

\u3068\u306a\u308a\u307e\u3059\uff08\u305d\u308c\u307b\u3069\u96e3\u3057\u3044\u8a71\u3067\u3082\u306a\u3044\u306e\u3067\uff0c\u5c0e\u51fa\u306f\u7701\u7565\u3057\u307e\u3059\uff09\uff0e\uff082020-12-11\uff1a\u3053\u306e\u5f0f\u3092\u8a02\u6b63…\u3072\u3069\u3044\u9593\u9055\u3044\u304c1\u5e74\u4ee5\u4e0a\u653e\u7f6e\u3055\u308c\u3066\u3044\u305f\u306a\u3041<\/small>\uff0e\uff09<\/ins><\/p>\n

\u305d\u3057\u3066\uff0cCu-K\u03b1<\/sub>\u7dda\u306eSi(111)\u9762\u306b\u3088\u308b\u53cd\u5c04\u306b\u3064\u3044\u3066\uff0ct<\/i> \u306e\u5024\u304c\u6b21\u306e\u3088\u3046\u306b\u8a08\u7b97\u3055\u308c\u308b\u3068\u8ff0\u3079\u3089\u308c\u3066\u3044\u307e\u3059\uff0e<\/p>\n

\u5bfe\u79f0\u53cd\u5c04\u6e2c\u5b9a\uff1a 38.4 \u03bcm
\n\u8584\u819c\u6cd5\u6e2c\u5b9a\uff08\u03b1<\/i> = 0.5\u00b0\uff09\uff1a2.7 \u03bcm<\/p><\/blockquote>\n

\u3053\u3053\u3067\u306f\uff0c\u305d\u308c\u3092\u5c0e\u3044\u3066\u307f\u307e\u3057\u3087\u3046\uff0e<\/p>\n

\u307e\u305a\uff0cSi(111)\u306e\u56de\u6298\u89d22\u03b8\u3092 28.42\u00b0\u3068\u3057\u307e\u3059\uff0e\u554f\u984c\u306f\u7dda\u5438\u53ce\u4fc2\u6570 \u03bc<\/i> \u3067\u3059\u304c\uff0c\u3053\u308c\u306f\u30ab\u30ea\u30c6\u30a3\u672c[2]\u306e\u4ed8\u93328\u3067\uff0c\u8cea\u91cf\u5438\u53ce\u4fc2\u6570 \u03bc<\/i>\/\u03c1<\/i> \u304c 65.32 cm2<\/sup>\/g \u3068\u3044\u3046\u5024\u304c\u4e0e\u3048\u3089\u308c\u3066\u3044\u307e\u3059\uff08\u305d\u306e\u51fa\u5178\u306f\uff0cInternational Tables for X-Ray Crystallography \u3060\u305d\u3046\u3067\u3059\uff09\uff0e\u3053\u308c\u306b\uff08\u5ba4\u6e29\u4ed8\u8fd1\u3067\u306e\uff09\u5bc6\u5ea6\u03c1<\/i> = 2.33 g\/cm3<\/sup> \u3092\u4e57\u3058\u3066\uff0c\u03bc<\/i> = 152 cm-1<\/sup> \u3068\u306a\u308a\u307e\u3059\uff08\u5ff5\u306e\u305f\u3081\u88dc\u8db3\u3059\u308b\u3068\uff0c\u3053\u308c\u306e\u9006\u6570\u3067\u3042\u308b 65.8 \u03bcm \u3092\u901a\u308b\u3068\uff0cCu-K\u03b1<\/sub>\u7dda\u304c e-1<\/sup> \u306b\u6e1b\u5f31\u3059\u308b\u3068\u3044\u3046\u3053\u3068\u3067\u3059\uff09\uff0e<\/p>\n

\u3053\u308c\u3089\u306e\u5024\u3092\u4ee3\u5165\u3057\u307e\u3057\u3087\u3046\uff0e\u5bfe\u79f0\u53cd\u5c04\u6e2c\u5b9a\u3068\u8584\u819c\u6cd5\u6e2c\u5b9a\uff08\u03b1<\/i> = 0.5\u00b0\uff09\u3067\uff0c\u305d\u308c\u305e\u308c 37.2 \u03bcm \u3068 2.60 \u03bcm \u306b\u306a\u308a\u307e\u3057\u305f\uff0e\u524d\u8ff0\u306e\u6587\u732e\u5024\u3068\uff0c3%\u307b\u3069\u306e\u5dee\u7570\u304c\u751f\u3058\u3066\u3044\u307e\u3059\uff0e\u56de\u6298\u89d2\u306f\u3069\u3093\u306a\u8cc7\u6599\u3067\u3082\u307b\u3068\u3093\u3069\u5909\u308f\u3089\u306a\u3044\u306e\u3067\uff0c\u8cea\u91cf\u5438\u53ce\u4fc2\u6570\u306e\u53c2\u7167\u5024\u306e\u9055\u3044\u3067\u3053\u306e\u5dee\u7570\u304c\u751f\u3058\u3066\u3044\u308b\u306e\u3067\u3057\u3087\u3046\uff0e\u3044\u305a\u308c\u306b\u3057\u3066\u3082\u3053\u306e\u304f\u3089\u3044\u306e\u30aa\u30fc\u30c0\u30fc\u3067\u3042\u308b\u3068\u3044\u3046\u3053\u3068\u306f\u9593\u9055\u3044\u306a\u3055\u305d\u3046\u3067\u3059\uff0e<\/p>\n

\u3053\u308c\u304c\uff0cSi(422)\u9762\uff082\u03b8 = 87.94\u00b0\uff09\u306b\u306a\u308b\u3068\u3069\u3046\u3067\u3057\u3087\u3046\u304b\uff0e\u8584\u819c\u6cd5\u6e2c\u5b9a\u3067\u306f2.62 \u03bcm \u3068\u307b\u3068\u3093\u3069\u5909\u308f\u3089\u306a\u3044\u306e\u306b\u5bfe\u3057\uff0c\u5bfe\u79f0\u53cd\u5c04\u3067\u306f 105 \u03bcm \u3068\uff0c(111)\u9762\u306b\u6bd4\u3079\u3066\u5927\u304d\u304f\u5909\u5316\u3057\u307e\u3059\uff0e<\/p>\n

\u307e\u3068\u3081\u308b\u3068\uff0c\u8584\u819c\u6cd5\u6e2c\u5b9a\uff08\u975e\u5bfe\u79f0\u53cd\u5c04\u6cd5\uff09\u306f\uff0c\u5bfe\u79f0\u53cd\u5c04\u6cd5\u306b\u6bd4\u3079\u3066\u4fb5\u5165\u6df1\u3055\u304c\u6d45\u3044\u3053\u3068\uff0c\u305d\u3057\u3066\u4fb5\u5165\u6df1\u3055\u304c2\u03b8<\/i>\u306b\u307b\u3068\u3093\u3069\u4f9d\u5b58\u3057\u306a\u3044\u3053\u3068\uff0c\u3053\u306e2\u70b9\u306b\u3088\u308a\uff0c\u8584\u819c\u306e\u5206\u6790\u306b\u9069\u3057\u305f\u65b9\u6cd5\u3067\u3042\u308b\u3068\u8a00\u3048\u307e\u3059\uff0e<\/p>\n

\u53c2\u8003\u6587\u732e<\/h3>\n
    \n
  1. \u5149\u6c38\u5fb9\uff0c\u8584\u819cX\u7dda\u6e2c\u5b9a\u6cd5 \u57fa\u790e\u8b1b\u5ea7 \u7b2c2\u56de Out-of-plane \u6e2c\u5b9a\uff0c\u30ea\u30ac\u30af\u30b8\u30e3\u30fc\u30ca\u30eb<\/a>39(1) 26-30, 2008<\/li>\n
  2. \u30ab\u30ea\u30c6\u30a3\u8457\u30fb\u677e\u6751\u6e90\u592a\u90ce\u8a33\u300c\u65b0\u7248 X\u7dda\u56de\u6298\u8981\u8ad6\u300d1980\uff0c\u30a2\u30b0\u30cd\u627f\u98a8\u793e<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

    X\u7dda\u56de\u6298\u6cd5\u3067\u306f\uff0c\u8a66\u6599\u8868\u9762\u304b\u3089\u3069\u306e\u7a0b\u5ea6\u306e\u6df1\u3055\u306e\u60c5\u5831\u304c\u5f97\u3089\u308c\u308b\u306e\u3067\u3057\u3087\u3046\u304b\uff1f<\/p>\n","protected":false},"author":38,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[6],"tags":[41,39,42,40],"class_list":["post-418","post","type-post","status-publish","format-standard","hentry","category-xrd","tag-gixd","tag-x","tag-42","tag-40"],"aioseo_notices":[],"aioseo_head":"\n\t\t\n\t\n\t\n\t\n\t\n\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t\n\t\t