{"id":125,"date":"2024-09-26T13:11:47","date_gmt":"2024-09-26T04:11:47","guid":{"rendered":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/?page_id=125"},"modified":"2026-05-21T18:08:46","modified_gmt":"2026-05-21T09:08:46","slug":"%e7%a0%94%e7%a9%b6%e6%a6%82%e8%a6%81","status":"publish","type":"page","link":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/%e7%a0%94%e7%a9%b6%e6%a6%82%e8%a6%81\/","title":{"rendered":"\u7814\u7a76\u6982\u8981"},"content":{"rendered":"<p>\u30fb\u6c34\u8cea\u3084\u5927\u6c17\u306e\u74b0\u5883\u6d44\u5316\u3092\u6307\u5411\u3057\u305f\u5149\u89e6\u5a92\u306e\u958b\u767a<\/p>\n<p>\u30fb\u30ab\u30fc\u30dc\u30f3\u30cb\u30e5\u30fc\u30c8\u30e9\u30eb\u306b\u8ca2\u732e\u3059\u308b\u6c34\u5206\u89e3\u6c34\u7d20\u751f\u6210\u5149\u89e6\u5a92\u306e\u958b\u767a<\/p>\n<p>\u5f53\u7814\u7a76\u5ba4\u3067\u306f\u3001\u4e0a\u8a18\u306e\u7814\u7a76\u3092\u4e2d\u5fc3\u3068\u3057\u305f\u5149\u5316\u5b66\u30fb\u6750\u6599\u5316\u5b66\u30fb\u5fdc\u7528\u5316\u5b66\u3092\u884c\u3063\u3066\u304a\u308a\u307e\u3059<\/p>\n<p>&nbsp;<\/p>\n<p style=\"text-align: left\">\u900f\u660e\u306a\u9178\u5316\u30c1\u30bf\u30f3(TiO<sub>2<\/sub>)\u30be\u30eb\u306b\u91d1\u5c5e\u30a4\u30aa\u30f3(Cr\u3001Pt\u3001Co\u306a\u3069)\u3092\u30c9\u30fc\u30d7\u3057\u3001UV-Vis-NIR\u5438\u53ce\u30b9\u30da\u30af\u30c8\u30eb\u3092\u6e2c\u5b9a\u3057\u305f\u7d50\u679c\u3001\u5404\u91d1\u5c5e\u30a4\u30aa\u30f3\u306b\u7531\u6765\u3055\u308c\u308b\u5438\u53ce\u30d4\u30fc\u30af\u3092\u78ba\u8a8d\u3067\u304d\u305f\u3053\u3068\u304b\u3089\u3001\u91d1\u5c5e\u30a4\u30aa\u30f3\u3092\u30c9\u30fc\u30d7\u3057\u305f\u900f\u660e\u306aTiO<sub>2<\/sub>\u30be\u30eb\u306e\u5408\u6210\u306b\u6210\u529f\u3057\u305f\u3002\u3042\u3044\u3061\u30b7\u30f3\u30af\u30ed\u30c8\u30ed\u30f3\u5149\u30bb\u30f3\u30bf\u30fc\u306eBL5S1\u306e\u30d3\u30fc\u30e0\u30e9\u30a4\u30f3\u3092\u7528\u3044\u305fX\u7dda\u5438\u53ce\u7aef\u8fd1\u508d\u69cb\u9020\u6e2c\u5b9a(XANES)\u3092\u884c\u3046\u3053\u3068\u3067\u3001TiO<sub>2<\/sub>\u30be\u30eb\u306b\u30c9\u30fc\u30d7\u3057\u305fPt\u30a4\u30aa\u30f3\u306e\u539f\u5b50\u4fa1\u72b6\u614b\u3092\u8abf\u67fb\u3057\u305f\u3002Pt-TiO<sub>2<\/sub>\u30be\u30eb\u306f\u7d2b\u5916\u5149\u7167\u5c04\u524d\u5f8c\u306e\u3044\u305a\u308c\u308211563 eV\u4ed8\u8fd1\u306b\u5438\u53ce\u30d4\u30fc\u30af\u304c\u51fa\u73fe\u3057\u305f\u304c\u3001\u7d2b\u5916\u5149\u7167\u5c04\u5f8c\u306e\u30d4\u30fc\u30af\u5f37\u5ea6\u306f\u5927\u304d\u304f\u6e1b\u5c11\u3057\u305f(\u56f31)\u3002\u3057\u305f\u304c\u3063\u3066\u3001\u7d2b\u5916\u5149\u7167\u5c04\u524d\u306ePt-TiO<sub>2<\/sub>\u30be\u30eb\u4e2d\u306ePt\u306e\u5927\u90e8\u5206\u306fPt(IV)\u72b6\u614b\u3001\u7d2b\u5916\u5149\u7167\u5c04\u5f8c\u306f\u3001\u307b\u307cPt(0)\u72b6\u614b\u3067\u5b58\u5728\u3059\u308b\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002\u3053\u306e\u7d50\u679c\u304b\u3089\u3001\u6c34\u306b\u5747\u4e00\u5206\u6563\u3057\u305fTiO<sub>2<\/sub>\u30be\u30eb\u306b\u304a\u3044\u3066\u3001\u7c89\u672b\u3068\u540c\u69d8\u306aXANES\u6e2c\u5b9a\u306b\u3088\u3063\u3066\u30c9\u30fc\u30d7\u3057\u305f\u91d1\u5c5e\u30a4\u30aa\u30f3\u306e\u539f\u5b50\u4fa1\u72b6\u614b\u304c\u78ba\u8a8d\u3067\u304d\u308b\u3053\u3068\u304c\u308f\u304b\u3063\u305f\u3002\u7d040.12 M\u306eTiO<sub>2<\/sub>\u30be\u30eb\u306b\u3001\u72a0\u7272\u5264\u3068\u3057\u3066\u785d\u9178\u9280\u3092\u6dfb\u52a0\u3057\u3001\u7d2b\u5916\u5149\u3092\u7167\u5c04\u3057\u305f\u3068\u3053\u308d\u3001\u7d040.8 \u03bcmol h<sup>-1<\/sup>\u306e\u9178\u7d20\u751f\u6210\u306b\u6210\u529f\u3057\u305f\u30022.0 atom%\u306eCo\u30a4\u30aa\u30f3<img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-251 alignright\" src=\"http:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-content\/uploads\/sites\/107\/XANES_.jpg\" alt=\"\" width=\"228\" height=\"280\" \/>\u3092\u52a9\u89e6\u5a92\u3068\u3057\u3066\u3001TiO<sub>2<\/sub>\u306b\u30c9\u30fc\u30d7\u3057\u305f\u3068\u3053\u308d\u3001\u7d041.7 \u03bcmol h<sup>-1<\/sup>\u3092\u8a18\u9332\u3057\u305f\u3002\u3055\u3089\u306b\u3001Cr-Pt-TiO<sub>2<\/sub>\u30be\u30eb\u306b\u30e1\u30bf\u30ce\u30fc\u30eb\u3092\u5171\u5b58\u3055\u305b\u3001\u53ef\u8996\u5149(\u03bb = 430 nm)\u3092\u7167\u5c04\u3059\u308b\u3053\u3068\u3067\u3001\u6c34\u7d20\u306e\u751f\u6210\u3092\u78ba\u8a8d\u3067\u304d\u305f\u3002\u7c89\u672b\u306eCr-Pt-TiO<sub>2<\/sub>\u3068\u6bd4\u8f03\u3057\u3066Cr-Pt-TiO<sub>2<\/sub>\u30be\u30eb\u306f\u3001\u5149\u6563\u4e71\u304c\u6291\u5236\u3055\u308c\u305f\u7d50\u679c\u3001\u6c34\u7d20\u767a\u751f\u306e\u521d\u671f\u901f\u5ea6\u306b\u5bfe\u3059\u308b\u5149\u89e6\u5a92\u6d3b\u6027\u3092\u7d042\u500d\u5411\u4e0a\u3055\u305b\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u305f\u3002TiO<sub>2<\/sub>\u30be\u30eb\u3001Co-TiO<sub>2<\/sub>\u30be\u30eb\u3001Cr-Pt-TiO\u2082\u30be\u30eb\u306e\u3044\u305a\u308c\u3082\u5149\u7167\u5c04\u5f8c\u3067\u3082\u900f\u660e\u6027\u3092\u7dad\u6301\u3057\u305f\u3002<br \/>\n\u672c\u7814\u7a76\u306f\u516c\u76ca\u8ca1\u56e3\u6cd5\u4ebaJKA\u306e\u52a9\u6210\u3092\u53d7\u3051\u3066\u5b9f\u65bd\u3057\u307e\u3057\u305f\u3002\u6df1\u304f\u611f\u8b1d\u7533\u3057\u4e0a\u3052\u307e\u3059\u3002<\/p>\n<p style=\"text-align: left\">\n","protected":false},"excerpt":{"rendered":"<p>\u30fb\u6c34\u8cea\u3084\u5927\u6c17\u306e\u74b0\u5883\u6d44\u5316\u3092\u6307\u5411\u3057\u305f\u5149\u89e6\u5a92\u306e\u958b\u767a \u30fb\u30ab\u30fc\u30dc\u30f3\u30cb\u30e5\u30fc\u30c8\u30e9\u30eb\u306b\u8ca2\u732e\u3059\u308b\u6c34\u5206\u89e3\u6c34\u7d20\u751f\u6210\u5149\u89e6\u5a92\u306e\u958b\u767a \u5f53\u7814\u7a76\u5ba4\u3067\u306f\u3001\u4e0a\u8a18\u306e\u7814\u7a76\u3092\u4e2d\u5fc3\u3068\u3057\u305f\u5149\u5316\u5b66\u30fb\u6750\u6599\u5316\u5b66\u30fb\u5fdc\u7528\u5316\u5b66\u3092\u884c\u3063\u3066\u304a\u308a\u307e\u3059 &nbsp; \u900f\u660e\u306a\u9178\u5316\u30c1\u30bf\u30f3(T&#8230;<\/p>\n","protected":false},"author":272,"featured_media":0,"parent":0,"menu_order":1,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"class_list":["post-125","page","type-page","status-publish","hentry"],"aioseo_notices":[],"_links":{"self":[{"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/pages\/125","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/comments?post=125"}],"version-history":[{"count":5,"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/pages\/125\/revisions"}],"predecessor-version":[{"id":252,"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/pages\/125\/revisions\/252"}],"wp:attachment":[{"href":"https:\/\/home.hirosaki-u.ac.jp\/photofunction\/wp-json\/wp\/v2\/media?parent=125"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}